Lime as a flocculation agent
One of the purposes of using lime is to enhance liquid-solid separation efficiency of sludge, i.e. remove bound water incorporated in the structure in which fine particles are dispersed (mutual repulsion by negative surface charges), in order to obtain a dryer and better workable sludge with enhanced storage properties (angle of repose).
By lime addition, particles are neutralised, destabilised and form micro-flocks first and then bulky floccules, which will settle.
 |
Lime addition as a chemical cationic agent

|
 |
| |
|
|
This flocculation effect is reinforced through the additional use of metal salts (from iron or alumina) and/or polymers.
Combined with lime, salts of Fe3+ and Al3+ through pH increase transform into amorphous gels Fe(OH)3 and Al(OH)3 which perform as inorganic polymers acting as bridge between particles.
 |
Polymers high molecular weight

Floc reinforcement by bridging |
 |